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美國布魯克海文儀器公司>技術文章>測量應用案例-20210606

技術文章

測量應用案例-20210606

閱讀:220          發布時間:2021-6-23
 

文獻名:Peroxymonosulfate activation through LED-induced ZnFe2O4 for levofloxacin degradation

 

 

作者:Yiwen Zhonga, Kaimin Shihd, Zenghui Diaoc, Gang Songa, Minhua Sua, Li'an Houa, Diyun Chena, Lingjun Kongab 

 

 

摘要:Recently, a lot of attentions were paid on sulfate (SO4-?) and hydroxyl (?OH) radicals-based advanced oxidation processes in degradation of fluoroquinolone antibiotic due to their favorable oxidation potential. This work reported an integrated peroxymonosulfate (PMS) activation process by coupling ZnFe2O4 (ZFO) with energy-saving LED for degradation and defluorination of levofloxacin (LEV). The LEV degradation efficiency reached 88.52 % within 180 min in the ZFO-500/LED/PMS system, which was higher than those of other activation systems. Both SO4-? and ?OH were generated in the integrated ZFO-500/LED/PMS system by the photo-generated electrons and holes activation of PMS under the LED irradiation. The recombination of photo-generated electrons and holes was reduced. Plenty of ?O2 and 1O2 were produced contributing to LEV degradation. The possible degradation pathways and mechanisms were proposed. This study presented a promising LED-assisted PMS activation process by ZnFe2O4 for antibiotic degradation.

 

關鍵詞:ZnFe2O4;Peroxymonosulfate;Levofloxacin;LED

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